Glycerol as an Efficient Medium for the Petasis Borono-Mannich Reaction

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Glycerol as an Efficient Medium for the Petasis Borono–Mannich Reaction

The multicomponent Petasis borono-Mannich (PBM) reaction is a useful tool for the preparation of complex molecules in a single step from boronic acids, aldehydes/ketones, and amines. Here, we describe the use of glycerol in the PBM reaction of salicylaldehydes or 2-pyridinecarbaldehyde with several boronic acids and secondary amines. From these readily available starting materials, alkylaminoph...

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Sulfonated polystyrene/montmorillonite nanocomposite (OMMT/PS-SO3H) was prepared and used as a novel, efficient and inexpensive heterogeneous acid catalyst in the one-pot reaction three-component Mannich reaction of ketones, aromatic aldehydes and amines under solvent-free conditions. The catalyst was characterized by XRD, SEM, TG, BET and FT-IR techniques. This method has advantages...

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Sulfonated polystyrene/montmorillonite nanocomposite as a new and efficient catalyst for the solvent-free Mannich reaction

Sulfonated polystyrene/montmorillonite nanocomposite (OMMT/PS-SO3H) was prepared and used as a novel, efficient and inexpensive heterogeneous acid catalyst in the one-pot reaction three-component Mannich reaction of ketones, aromatic aldehydes and amines under solvent-free conditions. The catalyst was characterized by XRD, SEM, TG, BET and FT-IR techniques. This method has advantages...

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sulfonated polystyrene/montmorillonite nanocomposite as a new and efficient catalyst for the solvent-free mannich reaction

sulfonated polystyrene/montmorillonite nanocomposite (ommt/ps-so3h) was prepared and used as a novel, efficient and inexpensive heterogeneous acid catalyst in the one-pot reaction three-component mannich reaction of ketones, aromatic aldehydes and amines under solvent-free conditions. the catalyst was characterized by xrd, sem, tg, bet and ft-ir techniques. this method has advantages of high yi...

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ژورنال

عنوان ژورنال: ChemistryOpen

سال: 2014

ISSN: 2191-1363

DOI: 10.1002/open.201402066